Publikationen

Aktuellste Publikation

Excess Charge Driven Dissociative Hydrogen Adsorption on Ti2O4ˉ
X. Song, M.R. Fagiani, S. Debnath, M. Gao, S. Maeda, T. Taketsugu, S. Gewinner, W. Schöllkopf, K.R. Asmis, A. Lyalin
Article in Phys. Chem. Chem. Phys. 19 23154-61 (2017)
DOI: 10.1039/C7CP03798H

Publikationen 2017

X. Song, M.R. Fagiani, S. Debnath, M. Gao, S. Maeda, T. Taketsugu, S. Gewinner, W. Schöllkopf, K.R. Asmis, A. Lyalin
Excess Charge Driven Dissociative Hydrogen Adsorption on Ti2O4ˉ
Phys. Chem. Chem. Phys.
DOI: 10.1039/C7CP03798H

M. Rohdenburg, M. Mayer, M. Grellmann, C. Jenne, T. Borrmann, F. Kleemiß, V.A. Azov, K.R. Asmis, S. Grabowsky, J. Warneke
Superelectrophilic Behavior of an Anion Demonstrated by Spontaneous Binding of [B12Cl1  1]⎺ with Noble Gases
Communication in Angew. Chem. Int. Ed. 56 7980-85 (2017)
DOI: 10.1002/anie.201702237   cover
press release (german)
M. Rohdenburg, M. Mayer, M. Grellmann, C. Jenne, T. Borrmann, F. Kleemiß, V.A. Azov, K.R. Asmis, S. Grabowsky, J. Warneke
Superelektrophiles Verhalten eines Anions demonstriert durch spontane Bindung von Edelgasen an [B12Cl11]⎺
Communication in Angew. Chem. 129 8090-6 (2017)
 DOI: 10.1002/ange.201702237  Titelbild

M.R. Fagiani, X. Song, S. Debnath, S. Gewinner, W. Schöllkopf, K.R. Asmis, F.A. Bischoff, F. Müller, J. Sauer
Dissociative Water Adsorption by Al3O4 + in the Gas Phase
Letter in J. Phys. Chem. Lett 8 1272-7 (2017)

DOI: 10.1021/acs.jpclett.7b00273

X. Song,  M.R. Fagiani, S. Gewinner, W. Schöllkopf, K.R. Asmis, F.A. Bischoff, F. Berger, J. Sauer
Gas Phase Vibrational Spectroscopy of the Aluminum Oxide Anions (Al2O3)1-6AlO2
Communication in ChemPhysChem 18 868-72 (2017)
DOI: 10.1002/cphc.201700089 cover

M.R. Fagiani, X. Song, P. Petkov, S. Debnath, S. Gewinner, W. Schöllkopf, T. Heine, A. Fielicke, K.R. Asmis
Structure and Fluxionality of B13+ Probed by Infrared Photodissociation Spectroscopy
Communication in Angew. Chem. Int. Ed. 56 501-4 (2017)

DOI: 10.1002/anie.201609766       cover
German press release (Universität Leipzig)
English press release (Fritz-Haber-Institut Berlin)

M.R. Fagiani, X. Song, P. Petkov, S. Debnath, S. Gewinner, W. Schöllkopf, T. Heine, A. Fielicke, K.R. Asmis
Untersuchung der Struktur und Dynamik des B13+ mithilfe der Infrarot-Photodissoziationsspektroskopie
Communication in Angew. Chem.  129 515-9 (2017)
DOI: 10.1002/ange.201609766       Titelbild

Publikationen 2016

C.T. Wolke, J.A. Fournier, L.C. Dzugan, M.R. Fagiani, T.T. Odbadrakh, H. Knorke, K.D. Jordan, A.B. McCoy, K. R. Asmis, M.A. Johnson
Spectroscopic snapshots of the proton transfer mechanism in water
Report in Science 354 1131-5  (2016)
DOI: 10.1126/science.aaf8425 
German press release
YouTube video
Perspective

M.R. Fagiani, H. Knorke, T. Esser, N. Heine, C.T. Wolke, S. Gewinner, W. Schöllkopf, M.-P. Gaigeot, R. Spezia, M.A. Johnson, K.R. Asmis
Gas Phase Vibrational Spectroscopy of the Protonated Water Pentamer: The Role of Isomers and Nuclear Quantum Effects
Phys. Chem. Chem. Phys. 18 26743-54 (2016)
DOI: 10.1039/C6CP05217G
E.C. Stanca-Kaposta, F. Schwaneberg, M.R. Fagiani, M. Lalanne, L. Wöste, K.R. Asmis
Infrared Photodissociation Spectroscopy of C4Nˉ, C6Nˉ and C8
Article in ChemPhysChem 17 3783-9 (2016)
 DOI: 10.1002/cphc.201600598
X. Song, M.R. Fagiani, S. Gewinner, W. Schöllkopf, K.R. Asmis, F.A. Bischoff, F. Berger, J. Sauer
Gas Phase Structures and Charge Localization in Small Aluminum Oxide Anions: Infrared Photodissociation Spectroscopy and Electronic Structure Calculations
Article in J. Chem. Phys. 144 244305 (2016)
 DOI: 10.1063/1.4954158
C. Appiah, K.R. Siefermann, M. Jorewitz, H. Barqawi, W.H. Binder
Synthesis and characterization of new photoswitchable azobenzene-containing poly(ε-caprolactones)
Article in RSC Adv. 6 6358-6367 (2016)
DOI: 10.1039/C5RA25216D

M.L. Weichman, X. Song, M.R. Fagiani, S. Debnath, D.M. Neumark, K.R. Asmis
Gas Phase Vibrational Spectroscopy of Cold (TiO2)n¯ (n=3-8) Clusters
Article in J. Chem. Phys. 144 124308 pp. 1-11  (2016)

DOI: 10.1063/1.4942194

T. Wende, N. Heine, T.I. Yacovitch, K.R. Asmis, D.M. Neumark, L. Jiang
Probing the Microsolvation of a Quaternary Ion Complex: Gas Phase Vibrational Spectroscopy of (NaSO4¯)2(H2O)n=0-8
Article in Phys. Chem. Chem. Phys. 18 267-77 (2016)
DOI: 10.1039/c5cp05762k

Publikationen 2015

N. Heine, M.R. Fagiani, K.R. Asmis
Disentangling the Contribution of Multiple Isomers to the Infrared Spectrum of the Protonated Water Heptamer
Letter in J. Phys. Chem. Lett. 6 2298-304 (2015)
DOI: 10.1021/acs.jpclett.5b00879
S.-T. Sun, L. Jiang, J.W. Liu, N. Heine, T.I. Yacovitch, T. Wende, K.R. Asmis, D.M. Neumark, Z.-F. Liu,
Microhydrated Dihydrogen Phosphate Clusters Probed by Gas Phase Vibrational Spectroscopy and First Principles Calculations
Article in Phys. Chem. Chem. Phys. 17  25714-24 (2015)
 DOI: 10.1039/C5CP02253C
C.T. Wolke, F.S. Menges, N.Tötsch, O. Gorlova, J.A. Fournier, G.H. Weddle, M.A. Johnson, N. Heine, T.K. Esser, H. Knorke, K.R. Asmis, A.B. McCoy , D.J. Arismendi-Arrieta, R. Prosmiti, F. Paesani
Thermodynamics of Water Dimer Dissociation in the Primary Hydration Shell of the Iodide Ion with Temperature-Dependent Vibrational Predissociation Spectroscopy
Article in J. Phys. Chem. A 119 1859-66 (2015)
DOI: 10.1021/jp510250n
M.R Fagiani, L.L. Zeonjuk, T.K. Esser, D. Gabel, T. Heine, K.R. Asmis, and J. Warneke
Opening of an Icosahedral Boron Framework: A Combined Infrared Spectroscopic and Computational Study
Editor's Choice Article in Chem. Phys. Lett. 625 48-52 (2015)
DOI: 10.1016/j.cplett.2015.02.030

N. Heine and K.R. Asmis
Cryogenic Ion Trap Vibrational Spectroscopy of Hydrogen-Bonded Clusters Relevant to Atmospheric Chemistry
Invited Review Article in Int. Rev. Phys. Chem. 34 1-34 (2015). Corrigendium:  35 507 (2016).
DOI: 10.1080/0144235X.2014.979659
DOI: 10.1080/0144235X.2016.1203533

Publikationen 2014

J.A. Fournier, C.T. Wolke, C.J. Johnson, M.A. Johnson, N. Heine, S. Gewinner, W. Schöllkopf, T.K. Esser, M.R. Fagiani, H. Knorke, K.R. Asmis, "Site-specific spectral signatures of water molecules in the “magic” H3O+(H2O)20 and Cs+(H2O)20 clusters in the regions of the OH(D) stretches and low frequency librations (215-1000 cm-1)". Article in PNAS 111  18132–7 (2014). doi: 10.1073/pnas.1420734111
G.B.S. Miller, T.K. Esser, H. Knorke, S. Gewinner, W. Schöllkopf, N. Heine, K.R. Asmis, E. Uggerud, „Spectroscopic Identification of a Bidentate Binding Motif in the Anionic Magnesium-CO2 Complex ([ClMgCO2]“. Communication in Angew. Chem. Int. Ed. 53 14407-10 (2014).  DOI: 10.1002/anie.201409444
T.M. Maier, A.D. Boese, J. Sauer, T. Wende, M. Fagiani, K.R. Asmis,"The vibrational spectrum of FeO2+ isomers-Theoretical benchmark and experiment". Article in J. Chem. Phys. 140 204315 (2014). DOI: 10.1063/1.4878667

E.C. Stanca-Kaposta, F. Schwaneberg, M.R. Fagiani, T. Wende, F. Hagemann, A. Wünschmann, L. Wöste, K.R. Asmis, "Infrared Photodissociation Spectroscopy of C2n+1N Anions with n = 1–5", Article in Z. Phys. Chem. 228 351-68 (2014). 

DOI: 10.1515/zpch-2014-0507

N. Heine, E.G. Kratz, R. Bergmann, D.P. Schofield, K.R. Asmis, K.D. Jordan, A.B. McCoy, "Vibrational Spectroscopy of the Water-Nitrate Complex in the O-H Stretching Region", Article in J. Phys. Chem. A 118 8188-97 (2014). DOI: 10.1021/jp500964j

N. Heine, T. Yacovitch, F. Schubert, C. Brieger, D.M. Neumark, K.R. Asmis "Infrared Photodissociation Spectroscopy of Microhydrated Nitrate-Nitric Acid Clusters NO3¯ (HNO3)m(H2O)n", Article in J. Phys. Chem. A 118 7613-22 (2014). DOI: 10.1021/jp412222q

L. Jiang, S.-T. Sun, N. Heine, J.-W. Liu, T.I. Yacovitch, T. Wende, Z.-F. Liu, D.M. Neumark, K.R. Asmis, "Large amplitude motion in cold monohydrated dihydrogen phosphate anion H2PO4-(H2O): infrared photodissociation spectroscopy combined with ab initio molecular dynamics simulations". Communication in Phys. Chem. Chem. Phys.16 1314-8 (2014). DOI:10.1039/C3CP54250E
Otero, I.; López, E. R.; Reichelt, M.;  Villanueva, M.; Salgado, J.; Fernández, J., "Ionic Liquids Based on Phosphonium Cations As Neat Lubricants or Lubricant Additives for a Steel/Steel Contact"
Appl. Mater. Interfaces, 6 (2014), 13115-13128
Otero, I.; López, E. R.; Reichelt, M.; Fernández, J.,"Tribo-chemical reactions of anion in pyrrolidinium salts for steel–steel contact"
Tribol. Int., 77 (2014), 160-170
Otero, I.; López, E. R.; Reichelt, M.; Fernández, J., "Friction and anti-wear properties of two tris(pentafluoroethyl)trifluorophosphate ionic liquids as neat lubricants"
Tribol. Int., 70 (2014), 104-111

Publikationen 2013

M. Wanko, T. Wende, M.M. Saralegui, L. Jiang, A. Rubio, K.R. Asmis, "Solvent-mediated folding in dicarboxylate dianions: aliphatic chain length dependence and origin of the IR intensity quenching", Article in Phys. Chem. Chem. Phys. 15 20463-72 (2013). DOI: 10.1039/c3cp52824c

T.I. Yacovitch, N. Heine, C. Brieger, T. Wende, C. Hock, D.M. Neumark, K.R. Asmis, "Vibrational Spectroscopy of Bisulfate/Sulfuric Acid/Water Clusters: Structure, Stability and IRMPD Intensities", Article in J. Phys. Chem. A 117 7081−90 (2013).

DOI: 10.1021/jp400154v

N. Heine, M.R. Fagiani, M. Rossi, T. Wende, G. Berden, V. Blum, K.R. Asmis, "Isomer-Selective Detection of Hydrogen-Bond Vibrations in the Protonated Water Hexamer", Article in J. Am. Chem. Soc. 135 8266–73 (2013). 

DOI: 10.1021/ja401359t

N. Dietl, T. Wende, K. Chen, L. Jiang, M. Schlangen, X. Zhang, K. Asmis, H. Schwarz, "Structure and Chemistry of the Heteronuclear Oxo-Cluster [VPO4]•+: A Model System for the Gas-phase Oxidation of Small Hydrocarbons", Article in J. Am. Chem. Soc. 135 3711−21 (2013). DOI: 10.1021/ja400198y

Publikationen 2008-2012

T.C. Cheng, L. Jiang, K.R. Asmis, Y. Wang, J.M. Bowman, A.M. Ricks, M.A. Duncan,

"Mid- and Far-IR Spectra of H5+ and D5+ Compared to the Predictions of Anharmonic Theory", Letter in J. Phys. Chem. Lett. 3 3160-6 (2012). DOI: 10.1021/jz301276f

E. Janssens, S.M. Lang, M. Brümmer, A. Niedziela, G. Santambrogio, K.R. Asmis, J.

Sauer, “Kinetic Study of the Reaction of Vanadium and Vanadium-Titanium Oxide Cluster

Anions with SO2“, Paper in Phys. Chem. Chem. Phys. 14 14344–53 (2012).

DOI: 10.1039/c2cp42201h

T.I. Yacovitch, N. Heine, C. Brieger, T. Wende, C. Hock, D.M. Neumark, K.R.

Asmis,“Vibrational Spectroscopy of Atmospherically Relevant Acid Cluster Anions
– Bisulfate Versus Nitrate Core Structures”
, Communication in J. Chem. Phys. 136
241102 1-4 (2012). DOI: 10.1063/1.4732148

K.R. Asmis, “Structure Characterization of Metal Oxide Clusters by Vibrational

Spectroscopy: Possibilities and Prospects”, Perspective in Phys. Chem. Chem. Phys. 14
9270-81 (2012). DOI: 10.1039/C2CP40762K

K.R. Asmis, T. Wende, M. Brümmer, O. Gause, G. Santambrogio, E.C. Stanca-Kaposta, J. Döbler, A. Niedziela, J. Sauer, “Structural Variability in Transition Metal Oxide Clusters: Gas Phase Vibrational Spectroscopy of V3O6-8+ ”, Article in Phys. Chem. Chem. Phys. 14 9377-88 (2012). DOI: 10.1039/C2CP40245A.

K.R. Asmis, D.M. Neumark, “Vibrational Spectroscopy of Microhydrated Conjugate Base Anions”, Invited Review Article in Accts. Chem. Res. 45 43-52 (2012).

DOI: 10.1021/ar2000748.

A.M. Burow, M. Sierka, R. Wlodarczyk, J. Sauer, T. Wende, P. Claes, L. Jiang, G. Meijer, P. Lievens, K.R. Asmis, “Structures and vibrational spectroscopy of partially reduced gas-phase cerium oxide clusters”, Article in Phys. Chem. Chem. Phys. 13 19393-400 (2011). DOI: 10.1039/c1cp22129a.
T.I. Yacovitch, T. Wende, L. Jiang, N. Heine, G. Meijer, D.M. Neumark, K.R. Asmis, “Infrared Spectroscopy of Hydrated Bisulfate Anion Clusters: HSO4-(H2O)1-16, Letter in J. Phys. Chem. Lett. 2 2135-40 (2011). DOI: 10.1021/jz200917f.
M. Savoca, T. Wende, L. Jiang, J. Langer, G. Meijer, O. Dopfer, K.R. Asmis, “Infrared Spectra and Structures of Silver-PAH Cation Complexes”, Letter in J. Phys. Chem. Lett. 2 2052-6 (2011). DOI: 10.1021/jz2009242.
L. Jiang, T. Wende, P. Claes, S. Bhattacharyy, M. Sierka , G. Meijer, P. Lievens, J. Sauer, K.R. Asmis, “Electron Distribution in Partially Reduced Mixed Metal Oxide Systems: Infrared Spectroscopy of CmVnOo+ Gas-Phase Clusters”, Article in J. Phys. Chem. A (Hobza Festschrift) 115 11187–92 (2011). DOI: 10.1021/jp203276g.
T. Wende, M. Wanko, L. Jiang, G. Meijer, K.R. Asmis, A. Rubio, “Spectroscopic Characterization of Solvent-Mediated Folding in Microhydrated Dicarboxylate Dianions”, Article in Angew. Chem. Int. Ed. 50 3807-10 (2011) DOI: 10.1002/anie.201006485 and Angew. Chem. 123 3891-4 (2011). DOI: 10.1002/ange.201006485.

L. Lin, P. Claes, T. Höltzl, E. Janssens, T. Wende, R. Bergmann, G. Santambrogio, G. Meijer, K.R. Asmis, M. T. Nguyen, P. Lievens, “The Structure of Au6Y+ in the Gas Phase”, Communication in Phys. Chem. Chem. Phys. 12 13907-13 (2010).

DOI: 10.1039/C0CP00911C.

T. Wende, J. Döbler, L. Jiang, P. Claes, E. Janssens, P. Lievens, G. Meijer, K.R. Asmis, J. Sauer, “Infrared Spectroscopic Characterization of the Oxidative Dehydrogenation of Propane by V4O10+, Invited Article in Int. J. Mass Spectrom. 297 102-6 (2010). DOI:10.1016/j.ijms.2010.06.033.
D.J. Goebbert, T. Wende, L. Jiang, G. Meijer, A. Sanov, K.R. Asmis “IR Spectroscopic Characterization of the Thermally Induced Isomerization in Carbon Disulfide Dimer Anions”, Letter in J. Phys. Chem. Lett. 1 2465–2469 (2010). DOI: 10.1021/jz100841e.
L. Jiang, T. Wende, R. Bergmann, G. Meijer, K.R. Asmis, “Gas-Phase Vibrational Spectroscopy of Microhydrated Magnesium Nitrate Ions [MgNO3(H2O)1-4]+, Article in J. Am. Chem. Soc. 132 7398–7404 (2010). DOI: 10.1021/ja1011806.
E. Garand, T. Wende, D.J. Goebbert, R. Bergmann, G. Meijer, D.M. Neumark, K.R. Asmis, "Infrared Spectroscopy of Hydrated Bicarbonate Anion Clusters: HCO3-(H2O)1-10, Article in J. Am. Chem. Soc. 132 849–856 (2010). DOI: 10.1021/ja9093132.

D.J. Goebbert, E. Garand, T. Wende, R. Bergmann, G. Meijer, K.R. Asmis, D.M. Neumark, "Spectroscopy of the Microhydrated Nitrate Ions NO3-(H2O)1-6", Article in J. Phys. Chem. A (R. Gerber Festschrift) 113 7584-7592 (2009).

DOI: 10.1021/jp9017103.

D.J. Goebbert, G. Meijer, K.R. Asmis, “10 K Ring Electrode Trap—Tandem Mass Spectrometer for Infrared Spectroscopy of Mass Selected Ions”, Article in AIP Conf. Proc. 1104 22 (2009).
D.J. Goebbert, T. Wende, R. Bergmann, G. Meijer, K.R. Asmis, “Messenger-Tagging Electrosprayed Ions: Vibrational Spectroscopy of Suberate Dianions", Article in J. Phys. Chem. A 113 5874-5880 (2009). DOI: 10.1021/jp809390x.
Y. Yang, O. Kühn, G. Santambrogio, D.J. Goebbert, K.R. Asmis, “Vibrational Signatures of Hydrogen Bonding in the Protonated Ammonia Clusters NH4+(NH3)1-4, Article in J. Chem. Phys.129 224302 1-8 (2008).
G. Santambrogio, E. Janssens, S. Li, T. Siebert, G. Meijer, K.R. Asmis, Jens Döbler, M. Sierka, J. Sauer, ”Identification of Conical Structures in Small Aluminum Oxide Clusters: Infrared Spectroscopy of (Al2O3)1−4(AlO)+, Article in J. Am. Chem. Soc. 130, 15143-15149 (2008). DOI: 10.1021/ja805216e.

G. Santambrogio, M. Brümmer, L. Wöste, J. Döbler, M. Sierka, J. Sauer, G. Meijer, K.R. Asmis, "Gas Phase Infrared Spectroscopy of Vanadium Oxide Cluster Anions", Article in Phys. Chem. Chem. Phys. 10, 3992-4005 (2008).

DOI: 10.1039/B803492C.

E. Garand, D. Goebbert, G. Santambrogio, E. Janssens, P. Lievens, G. Meijer, D. M. Neumark, K.R. Asmis, “Vibrational Spectra of Small Silicon Monoxide Cluster Cations Measured by Infrared Multiple Photon Dissociation Spectroscopy”, Article in Phys. Chem. Chem. Phys. 10, 1502-6 (2008). DOI: 10.1039/B716627C.

Publikationen 2003-2007

K.R. Asmis, Y. Yang, G. Santambrogio, M. Brümmer, L.R. McCunn, M.A. Johnson, O. Kühn, "Gas Phase Infrared Spectroscopy and Multidimensional Calculations of the Protonated Ammonia Dimer N2H7+", Communication in Angew. Chem. Int. Ed. 46, 8691-4 (2007).DOI: 10.1002/anie.200702607.

Y. Miller, G.M. Chaban, J. Zhou, G. Santambrogio, K.R. Asmis, D.M. Neumark, R.B. Gerber, “Vibrational Spectroscopy of (SO42-)·(H2O)Clusters, n=1-5: Harmonic and Anharmonic Calculations, and Experiment”, Article in J. Chem. Phys. 127, 094305-1-11 (2007).
S. Feyel, H. Schwarz, D. Schröder, C. Daniel, H. Hartl, J. Döbler, J. Sauer, G. Santambrogio, L. Wöste, and K.R. Asmis, “Gas-Phase Infrared Photodissociation Spectroscopy of Tetravanadium-oxo and –oxomethoxo Cluster-Anions”, Communication in ChemPhysChem8 1640-7 (2007).
K.R. Asmis, J. Sauer, "Mass-selective Vibrational Spectroscopy of Vanadium Oxide Clusters”, Invited Review Article in Mass. Spectrom. Rev. 26, 542-62 (2007).
K.R. Asmis, G. Santambrogio, J. Zhou, E. Garand, J. Headrick, D. Goebbert, M.A. Johnson, D.M. Neumark, “Vibrational Spectroscopy of Hydrated Electron Clusters (H2O)15-50¯ via Infrared Multiple Photon Dissociation”, Communication to J. Chem. Phys. 126, 191105-1-5 (2007). DOI:10.1063/1.2741508.

M. Sierka, J. Döbler, J. Sauer, G. Santambrogio, M. Brümmer, L. Wöste, E. Jannsens, G. Meijer, K.R. Asmis, "Unexpected Structures of Aluminum Oxide Clusters in the Gas Phase", Communication in Angew. Chem. Int. Ed46, 3372-5 (2007).

DOI: 10.1002/anie.200604823.

J. Zhou, G. Santambrogio, M. Brümmer, D.T. Moore, L. Wöste, G. Meijer, D.M. Neumark, K.R. Asmis, "Probing the Stepwise Solvation of the Sulfate Dianion: Gas Phase Infrared Spectroscopy of (SO42)·(H2O)n Clusters (n=3-24)", Communication in J. Chem. Phys. 125, 111102-1-4 (2006).
E. Janssens, G. Santambrogio, M. Brümmer, L. Wöste, P. Lievens, J. Sauer, G. Meijer, K.R. Asmis, "Isomorphous Substitution in Bimetallic Oxide Clusters", Letter in Phys. Rev. Lett. 96, 233401-233404 (2006).

K.R. Asmis, G. Santambrogio, M. Brümmer, J. Sauer, "Polyhedral Vanadium Oxide Cages: Infrared Spectra of Cluster Anions and Size-Induced d-Electron Localization", Communication in Angew. Chem. Int. Ed44, 3122-3125 (2005).

DOI: 10.1002/anie.200462894.

M.J. Nee, C. Kaposta, A. Osterwalder, C. Cibrián Uhalte, T. Xie, A. Kaledin, S. Carter, J.M. Bowman, D.M. Neumark, K.R. Asmis, "Experimental and theoretical study of the infrared spectra of BrHI¯ and BrDI¯", Article in J. Chem. Phys. 121, 7259-7268 (2004).
K.R. Asmis, M. Brümmer, C. Kaposta, G. Santambrogio, J. Sauer, G. Meijer, and L. Wöste, "Infrared Vibrational Predissociation Spectroscopy of Mono- and Divanadium Oxide Cluster Cations: A Combined Experimental and Ab Initio Study”, Article in J. Chem. Phys. 120, 6461-6470 (2004).
M. Brümmer, C. Kaposta, G. Santambrogio, K.R. Asmis, "Formation and Photodepletion of Cluster Ion–Messenger Atom Complexes in a Cold Ion Trap: Infrared Spectroscopy of VO+, VO2+ and VO3+", Communication in J. Chem. Phys. 119, 12700-12703 (2003).

H. Haberkern, K.R. Asmis, M. Allan, P. Swiderek, "Triplet states in Oligomeric Materials: Electron Energy Loss Spectroscopy of Thiophene and Bithiophene and Extrapolation to the Polymer", Article in Phys. Chem. Chem. Phys. 5, 827-833 (2003).

DOI: 10.1039/B210845C.

K.R. Asmis, N.L. Pivonka, G. Santambrogio, M. Brümmer, C. Kaposta, D.M. Neumark, L. Wöste, "The Gas-Phase Infrared Spectrum of the Protonated Water Dimer", Report in Science 299, 1375-1377 (2003). DOI:10.1126/science.1081634.
N.L. Pivonka, C. Kaposta, M. Brümmer, G. von Helden, G. Meijer, L. Wöste, D.M. Neumark, K.R. Asmis, "Probing a Strong Hydrogen Bond with Infrared Spectroscopy: Vibrational Predissociation of BrHBr¯•Ar", Communication in J. Chem. Phys. 118, 5275-5278 (2003).

Publikationen 1998-2002

N.L. Pivonka, C. Kaposta, G. von Helden, G. Meijer, L. Wöste, D.M. Neumark, K.R. Asmis, "Gas Phase Infrared Spectroscopy of Cluster Anions as a Function of Size: The Effect of Solvation on Hydrogen-Bonding in Br¯(HBr)1,2,3 Clusters", Full article in J. Chem. Phys. 117, 6493-6499 (2002).

K.R. Asmis, M. Brümmer, C. Kaposta, G. Santambrogio, G. von Helden, G. Meijer, K. Rademann, L. Wöste, "Mass-selected Infrared Photodissociation Spectroscopy of V4O10+", Communication in Phys. Chem. Chem. Phys. 4, 1101-1104 (2002).

DOI: 10.1039/B111056J.

H. Hess, K.R. Asmis, T. Leisner, L. Wöste, "Vibrational Wave Packet Dynamics in the Silver Tetramer Probed by NeNePo Femtosecond Pump-Probe Spectroscopy", Article in Eur. Phys. J. D 16, 145-149 (2001).
T.R. Taylor, H. Gomez, K.R. Asmis, D.M. Neumark, "Photoelectron Spectroscopy of GaX2¯, Ga2X¯, Ga2X2¯, and Ga2X3¯ (X = P, As)", Article in J. Chem. Phys. 115, 4620-4631 (2001).
K.R. Asmis, T.R. Taylor, D.M. Neumark, "Anion Photoelectron Spectroscopy of Small Boron Nitride Clusters: Adiabatic Detachment Energies and Vibrational Frequencies of B2N and B3N", Article in Eur. Phys. J. D 9, 257-261 (1999).
T.R. Taylor, K.R. Asmis, H. Gomez, D.M. Neumark, "Vibrationally Resolved Anion Photoelectron Spectra of the Low Lying Electronic States of GaP2¯, Ga2P¯ and Ga2P3¯", Article in Eur. Phys. J. D 9, 317-21 (1999).
K.R. Asmis, T.R. Taylor, D.M. Neumark, "Anion Photoelectron Spectroscopy of B3N¯", Article in J. Chem. Phys. 111, 10491-10500 (1999).
K.R. Asmis, T.R. Taylor, D.M. Neumark, "Anion Photoelectron Spectroscopy of B2N¯", Article in J. Chem. Phys. 111, 8838-8851 (1999).
K.R. Asmis, T.R. Taylor, D.M. Neumark, "Electronic Structure of Indium Phosphide Clusters: Anion Photoelectron Spectroscopy of InxPx¯ and Inx+1Px¯ (x = 1-13) Clusters", Article in Chem. Phys. Lett. 308, 347-354 (1999).
T.R. Taylor, K.R. Asmis, M.T. Zanni, D.M. Neumark, "Characterization of the I3 Radical by Anion Photoelectron Spectroscopy", Communication in J. Chem. Phys. 110, 7607-9 (1999).
T.R. Taylor, R.T. Bise, K.R. Asmis, D.M. Neumark, "The Singlet-Triplet Splittings of NCN", Article in Chem. Phys. Lett. 301, 413-6 (1999).
T.R. Taylor, K.R. Asmis, C. Xu, D.M. Neumark, "Evolution of Electronic Structure as a Function of Size in Gallium Phosphide Semiconductor Clusters", Article in Chem. Phys. Lett. 297, 133-40 (1998).
T. Lenzer, M.R. Furlanetto, K.R. Asmis, D.M. Neumark, "Zero Electron Kinetic Energy and Photoelectron Spectroscopy of the XeI¯ Anion", Article in J. Chem. Phys. 109, 10754-10766 (1998).
K.R. Asmis, T.R. Taylor, D.M. Neumark, "Anion Photoelectron Spectroscopy of BN¯ ", Article in Chem. Phys. Lett. 295, 75-81 (1998).
K.R. Asmis, T.R. Taylor, C. Xu, .M. Neumark, "Anion Photoelectron Spectroscopy of I2¯·Arn (n = 0 - 14, 16, 20) Clusters", Article in J. Chem. Phys. 109, 4389-4395 (1998).

V. Huber, K.R. Asmis, A.-C. Sergenton, M. Allan, S. Grimme , "Electron-Energy-Loss and DFT/SCI Study of the Singlet and Triplet Excited States and Electron Attachment Energies of Tetramethylsilane, Hexamethyldisilane, Tris-(trimethylsilyl)-Silane, and Tetra-Methoxysilane", Article in J. Chem. Phys. A 102, 3524-3531 (1998).

DOI: 10.1021/jp980537n.

Publikationen 1993-1997

K.R. Asmis, M. Allan, "Measurement of Absolute Differential Cross Sections for the Excitation of the p,p* Triplet State of Ethene by Electron Impact at 0 and 180 Degrees", Article in J. Chem. Phys. 106, 7044-7046 (1997).
K.R. Asmis, M. Allan, "Measurement of Absolute Differential Cross Sections for the Excitation of the n = 2 States of Helium at 0 and 180 Degrees", Article in J. Phys. B 30, 1961-1974 (1997).
K.R. Asmis, M. Allan, "Excess Energy Partition Between Electrons Departing at 0 and 180 Degrees in the Ionization of Helium Near Threshold", Letter in J. Phys. B 30, L167-173 (1997).
K.R. Asmis, M. Allan, M. Fülscher, "Electron Energy-Loss Spectroscopy and Theoretical Study of Triplet and Singlet Excited States of Fulvene", Article in J. Phys. Chem. A 101, 2089-2095 (1997). DOI: 10.1021/jp963129x.
M. Allan, K.R. Asmis, D.B. Popovic, M. Stepanovic, N.J. Mason, J.A. Davies, "Resonances in Collisions of Low-Energy Electrons with Ozone: Experimental Elastic and Vibrationally Inelastic Differential Cross Sections and Dissociative Attachment Spectra", Article in J. Phys. B 29, 4727-4747 (1996).
M. Allan, K.R. Asmis, D.B. Popovic, M. Stepanovic, N.J. Mason, J.A. Davies, "Production of Vibrationally Autodetaching O2¯ Produced in Low-Energy Electron Impact on Ozone", Article in J. Phys. B 29, 3487-3495 (1996).
L.Truttmann, K.R. Asmis, T. Bally, "Electronic and Vibrational Structure and Scaled Density Functional Force Field of Cyclopentadiene and Its Radical Cation", Article in J. Phys. Chem. 99, 17844-17851 (1995). DOI: 10.1021/j100051a008.
M.Allan, K.R. Asmis, S.El houar, E. Haselbach, M.Capponi, B. Urwyler, J. Wirz, "Triplet Energy of 2,2-Dimethylisoindene from Electron Energy-Loss Spectroscopy and Photoinduced Triplet Energy Transfer", Article in Helv. Chim. Acta 77, 1541-1548 (1994).
J.M. Smith, D.A. Hrovat, W.T. Borden, M. Allan, K.R. Asmis, C. Bulliard, E. Haselbach, U.C. Meier, "Synthesis and Spectroscopy of Tricycloundec-3(7)-ene:
Confirmation of Computational Predictions Regarding the Effects of Pyramidalization on Alkene Ionization Energies and Electron Affinities"
, Note in J. Am. Chem. Soc. 115, 3816-3817 (1993).

M. Allan, K. Asmis, C. Bulliard, E. Haselbach, P. Suppan, "Triplet-State Energy of the Photostabilizer Tinuvin P”, Article in Helv. Chim. Acta 76, 993-994 (1993).

akademische Publikationen

"Infrared Photodissociation Spectroscopy of Mass-Selected Cluster Ions in the Gas Phase", Habilitationsschrift, Institut für Experimentalphysik, Freie Universität Berlin (2005).
"Electron-Molecule Collision: A Novel Instrument for Measuring Inelastic Differential Cross Sections at 180° Angle and Applications", Doktorarbeit, Nr. 1142, Universität Freiburg i.Ü. (1996).
"Characterization of Complex Formation in the Gas Phase Using Fourier-Transform-IR-Spectroscopy", Diplomarbeit, Institut für Anorganische Chemie, Universität Freiburg i.Ü. (1992).

"Characterization of Excited States of Neutral Molecules and Their Negativley and Positively Charged Ions Using UV-Photoelectron and Electron-Impact-Spectroscopy", Diplomarbeit, Institut für Physikalische Chemie, Universität Freiburg i.Ü. (1992).

weitere Publikationen

K.R. Asmis, A. Fielicke, G. Meijer, G. von Helden, "Vibrational Spectroscopy of Clusters and Cluster-Adsorbate Complexes in the Gas Phase”
Chapter in Atomic Clusters: From Gas Phase to Deposited, edited by D.P. Woodruff; Vol. 12 of The Chemical Physics of Solid Surfaces, edited by D.P. Woodruff (Elsevier, Amsterdam, The Netherlands, 2007), ISBN 978-0-444-52756-1.
K.R. Asmis, D.M. Neumark, J.M. Bowman, "Gas Phase Vibrational Spectroscopy of Strong Hydrogen Bonds”, Chapter in Physical and Chemical Aspects I-III edited by J.T. Hynes, J.P. Klinman, H.-H. Limbach, R.L. Schowen; Vol. 1 of Hydrogen Transfer Reactions, edited by J.T. Hynes, J.P. Klinman, H.-H. Limbach, R.L. Schowen (Wiley-VCH, Weinheim, Germany, 2007), ISBN 978-3-527-30777-7.

K. Asmis, O. Kühn, "Bausteine des Wassers unter der Laserlupe”
Article in fundiert - Das Wissenschaftsmagazin der Freien Universität Berlin 2, 84 (2004).

letzte Änderung: 30.08.2017

Artbeitskreis Asmis

Kontakt

Leiter des Arbeitskreises
Prof. Dr. Knut R. Asmis
Raum TA 436
Linnéstr. 3
D-04103 Leipzig

Telefon: 0341-97 36421
E-Mail

Sekretariat
Wilhelm-Ostwald-Institut
Frau Kerstin Schleinitz

Telefon: 0341 97-36500
Telefax: 0341 97-36399
E-Mail

Postanschrift
Universität Leipzig
Wilhelm-Ostwald-Institut für Physikalische und Theoretische Chemie
Linnéstr. 2
D-04103 Leipzig